Abstract

Hydrogen-induced cracking was investigated by TEMin-situ tension in hydrogenated stainless steel of type 310. It was found experimentally that hydrogen-induced cracking happens via nanovoid nucleation followed by quasi-cleavage along {111} planes whenC H is higher. Otherwise, in the case of lowerC H, hydrogen enhances ductile fracture via hydrogen-enhanced microvoid nucleation, growth and connection. A new model was proposed based on the present experiments. Dislocations break away from defect atmospheres and move away from the DFZ, leaving vacancy and hydrogen clusters along {111} planes. Hydrogen tends to combine with vacancy clusters and initiate nanovoids along {111} planes. Dense nanovoids connect each other, resulting in brittle cracking. Scattered nanovoids grow into microvoids or even macrovoids, leading to ductile fracture.

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