Hydrogen from steam methane reforming by catalytic nonthermal plasma using a dielectric barrier discharge reactor

Abstract

AbstractA scaled‐up dielectric barrier discharge (DBD) reactor has been developed and demonstrated for the production of hydrogen from steam methane reforming (SMR) by catalytic nonthermal plasma (CNTP) technology. Compared to SMR, CNTP offers conversion at ambient pressure (101.325 kPa), low temperature with better efficiency, making it suitable for distributed hydrogen production with small footprint. There have been several lab‐scale DBD reactors reported in the literature. Dimension of the scaled‐up DBD reactor is about six times the lab‐scale version and can produce 0.9 kg H2/day. The scale‐up is, however, nonlinear; several technical innovations were required including spray nozzle for homogeneous introduction of steam, perforated tube central electrodes for generation of homogeneous plasma. Conversion efficiency of the scaled‐up DBD reactor is 70–80% at 550°C and 500 W. A continuous run of 8 hr was demonstrated with typical product gas composition of 69% H2, 6% CO2, 15% CO, 10% CH4.