Abstract
Abstract Alkyl phenyl sulfilimines, benzyl phenyl sulfilimine and the corresponding sulfoximines were found to exchange their α-hydrogens with deuteriums in heavy water when the medium was alkaline. No exchange was observed when the medium was acidic or neutral. The rates of exchange in a sulfilimine were greater than those of the corresponding sulfoximine. The kinetics of these H-D exchange reactions were investigated by use of pyridine as a catalyst, and the reaction mechanism was discussed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
