Hydrogen enhanced localized plasticity in zirconium as observed by digital image correlation

Abstract

Hydrogen embrittlement in zirconium alloys is a highly relevant research topic, important for ensuring the integrity of nuclear fuel clads. While the presence of hydrides in zirconium-based clad is a well-known risk factor due to their brittleness, the effect of the presence of hydrogen in solid solution is unclear.According to the Hydrogen Enhanced Localized Plasticity (HELP) model, hydrogen in solid solution may affect the mechanical performance of a metal by increasing dislocation mobility due to the shielding effect that hydrogen has on the interaction of dislocations with other types of defects. In the presented work, the presence of HELP has been assessed in Zircaloy-4 samples, under conditions relevant to the storage of spent nuclear fuel.Elevated temperature tensile tests were performed on samples containing localized areas of higher hydrogen concentration, as quantified by neutron radiography. Digital Image Correlation (DIC) analysis was performed on the specimen surfaces for quantitative characterization of strain heterogeneity during deformation to identify the regions where the plastic strain localization occurs.These regions could be correlated to elevated amounts of hydrogen in solid solution, that is, in the location immediately adjacent to dissolving hydrides, or in the areas of the samples with local hydrogen concentration close to the expected terminal solid solubility limit (TSS) in the test conditions.The results confirm the presence of localized softening caused by solid solution hydrogen, indicating that the HELP mechanism needs to be taken into account when modeling the mechanical response of zirconium-based nuclear fuel clads at elevated temperatures.