Hydrogen diffusion kinetics in dual-phase (DP 980) steel: The role of pre-strain and tensile stress

Abstract

The current study investigates the influence of pre-strain (un-strained, 3 %, and 6 % engineering strain) and in-situ tensile stress (50 %, 110 %, and 125 % of the yield stress (YS)) on the hydrogen diffusion and trapping behaviour in DP 980 steel. Electrochemical hydrogen permeation tests were conducted using a custom-built Devanathan-Stachurski (DS) cell integrated with a horizontal tensometer. The results showed that the value of apparent diffusion coefficient (Dapp) decreased from 5.4 ± 0.1 to 3.8 ± 0.029 × 10−7 cm2 s−1, while trap density (NT) and sub-surface hydrogen concentration (Capp) increased from 1.08 ± 0.01 to 1.58 ± 0.012 × 1021 cm−3, 2.70 ± 0.13 to 3.27 ± 0.10 × 10−4 mol H cm−3, respectively for unstrained and 6 % pre-strain conditions. This is due to increased dislocation density in ferrite and martensite. Hydrogen permeation tests under tensile stress (in-situ) revealed that the applied elastic stress of 50 % of YS showed a slight increase in Dapp and a decrease in NT values. This is due to an increase in the interstitial space between the atoms at applied elastic load favouring hydrogen diffusion. The plastic tensile stress of 110 % of YS showed the highest value of steady-state permeation current density iss (169 ± 10.6 µA cm−2). It could be due to an expanded lattice of martensite accommodating more hydrogen because of its elastic deformation. The tensile stress of 125 % of YS results in a significant reduction in Dapp (2.86 × 10−7 cm2 s−1) and an increase in Capp (5.52 × 10−4 mol H cm−3) and NT (2.11 × 1021 cm−3) as a result of plastic deformation in ferrite and martensite. The decay transient studies revealed that the applied elastic tensile stress enhances the rate of desorption of diffusible hydrogen, increasing lattice diffusion coefficient DL. The plastic pre-strain and plastic tensile stress resulted in slower desorption, lower DL, and an increase in reversible trap density.