Abstract

The influence of electrolytical hydrogenation on fracture toughness, corrosion crack-growth resistance and fracture micromechanisms of operated 12Cr1MoV steel of thermal power plant superheater collector has been studied. Compact tension specimens were cut from perforated surface of thermal power plant superheater collector dismounted after 178,500hours of operation.Corrosion crack-growth resistance under tension of previously hydrogenated compact specimens with fatigue cracks was studied. Due to the increased concentration of hydrogen in solution an additional buffer was being created that prevents hydrogen leakage from the specimen through the fracture surface during the experiment.The hydrogenation causes the significant decrease of critical stress intensity factor Kc, during the experiment in 0.1N NaOH solution as compared with critical stress intensity factor K of non-hydrogenation 12Cr1MoV steel obtained by the 5% secant line method and in comparison with critical stress intensity factor Kc, determined through the J-integral.The areas of ductile crack growth in hydrogenated and non-hydrogenated specimens were found to have similar material fracture micromechanisms with dimples creation of different shape and size. But on the ductile crack growth area in hydrogenated specimens material intergranular fracture mechanisms were found caused by the hydrogen embrittlement which are similar to areas without ridges with the products corrosion traces.

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