Abstract
AbstractWe have developed an efficient and straightforward hydrogen‐bonding‐network‐assisted regioselective sulfenylation and trifluoromethylthiolation of electron‐rich arenes using the electrophilic SCF3 reagent and N‐thiosuccinimides. This catalyst‐free protocol offers good yields for a wide range of arenes and shows good functional group tolerance without any protecting groups.
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