Abstract

The equilibrium constants of the hydrogen bonding (HB) between hydroxylic donors, ROH, and an MLCT-excited Ru(bpy)2(bpz)2+ complex, 1(T), correlated with ROH empirical HB acidities, which could be used for evaluating the unimolecular rate constants of concerted electron-proton transfer within the H-bonded phenol-1(T) exciplexes.

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