Abstract

Iod hat die Wahl: Ein C2-symmetrischer Organoiod(III)-Katalysator mit flexibler Konformation wurde für die enantioselektive oxidative Desaromatisierung von Phenolen entwickelt. Der Verlauf der Katalyse wird durch intramolekulare Wasserstoffbrücken und den zugesetzten achiralen Alkohol gesteuert.

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