Abstract

The crystal structure of 2:1 TCNQ salt of 2-methyl-5-phenyl-7,9-dichloro-1,6-diazaphenalene (1) was investigated for the construction of new hydrogen-bonded charge-transfer complexes. This salt was composed of neutral1, protonated1 (1·H+) and ionic TCNQ (TCNQ.−), and constructed a segregated structure with uniform π-stackings. The N-H…N≡C hydrogenbonding between1/1·H+ and TCNQ.− formed the D-A-D triad, and connected the columnar structures.

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