Abstract

Three kinds of trinuclear metal string complexes, [Ni3(dpa)4(L1)2] · H2O · C2H5OH (L1 = (E)-3-(2-hydroxyl-phenyl)-acrylic acid) (1), [Ni3(dpa)4(L2)2] · 2C2H5OC2H5 (L2 = (E)-3-(3-hydroxyl-phenyl)-acrylic acid) (2) and [Ni3(dpa)4(L3)2] · 3CH2Cl2 · 1.5CH3OH (L3 = (E)-3-(4-hydroxyl-phenyl)-acrylic acid) (3). (dpa− = bis(2-pyridyl)amido), have been synthesized. The structures of 1 and 2 have been analyzed by the X-ray single-crystal diffraction showing hydrogen-bonded networks.

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