Abstract

The atmosphere controlled high temperature mass spectrometer has provided the vapor pressure data for a promising tritium breeding material, Li2TiO3, under condition of low-pressure hydrogen atmosphere. The observed vaporization behavior of Li2TiO3 under hydrogen addition is presented here. It was pointed out that hydrogen addition may cause formation of non-stoichiometric composition phase. For elucidating its possible non-stoichiometric character, the composition of Li2TiO3 has been investigated mainly by means of thermogravimetry. The results revealed that Li2TiO3 has doubly non-stoichiometric composition, Li2-xTiO3-y

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