Hydrogen and LNG production from coke oven gas with multi-stage helium expansion refrigeration

Abstract

Here we propose a novel cryogenic system to simultaneously produce liquid hydrogen (LH2) and liquefied natural gas (LNG) from coke oven gas. The coke oven gas, simplified as a mixture of methane and hydrogen, directly enters the cryogenic system. Due to the very low temperature of liquid hydrogen, helium is selected as the refrigerant, and the energy needed for the liquefaction is supplied by a multi-stage helium expansion refrigeration system. The high-purity liquid hydrogen and LNG products are obtained with the help of a cryogenic distillation column. The whole cryogenic process is simulated with the Aspen HYSYS software to determine the parameters of each process point and key component. We found that the process is able to produce LH2 and LNG of very high purity. Using the power consumption of the product liquefaction as the major performance parameter for the analysis, optimum parameters of the multi-stage helium expansion liquefaction process could be found. The results show that the proposed system can achieve a methane recovery rate of 97.9% and a hydrogen recovery rate of 99.7% with acceptable energy consumption.