Abstract
With dimethyl mercury and dimethyl cadmium as sources of methyl radicals, values of k1/k21/2 for the reactions [Formula: see text] [Formula: see text]have been calculated from 471 to 527 °C over the pressure range 0.3 to 16.2 cm. Extrapolation to the effective infinite pressure region, where it is assumed that E2 = 0, gives E1 = 9.3 kcal mole−1, log A1 = 10.8 (cc mole−1 s−1).
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