Abstract
A study of the hydroformylation of styrene, α-methylstyrene, allylbenzene and trans-propenylbenzene catalysed by octacarbonyldicobalt has shown that use of pyridine as a catalyst activator has a marked influence on the selectivity of the reaction and that the isomeric composition of the aldehydes is strongly dependent upon the temperature. Deuterium scrambling was observed in the hydrogenation and hydroformylation products concurrently formed from 2-phenylpropene-1 d 2-3 d 3 even at p(CO) 100 atm.
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