Abstract

Different micellar systems are characterized. Hydroformylation reactions are carried out in the most appropriate ones and are compared with hydroformylations in a non-micellar system. Reaction rates and selectivities for aldehydes are higher than the micelles. In addition to this, olefins between C 6 and C 16 are successfully hydroformylated in the micellar system, whereas C 8 is the highest olefin that can be hydroformylated without micelles. The behavior of the reaction in the micellar system is very sensitive to the initial composition and reaction conditions.

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