Hydrodynamics and Axial Dispersion in a Gas−Liquid−(Solid) EL-ALR with Different Sparger Designs

Abstract

The gas−liquid−(solid) three-phase hydrodynamics in an external-loop airlift reactor (EL-ALR) with an upward pipe 0.47 m in diameter and 2.5 m in height, two external loop downward pipes 0.08 m in diameter and 2.5 m in height, were investigated using four different gas sparger designs. The microconductivity probe and the three-dimensional (3-D) laser Doppler anemometry (LDA) techniques were, respectively, implemented to measure the local gas holdup in the riser (αGr) and liquid phase velocity in the downcomer (ULd) using air as the gas phase, water as the liquid phase, and alginate gel beads as the solid phase, over a wide range of operation conditions. The tracer age distribution was measured using the pulse-pursuit response technology. Axial dispersion model (ADM) was used to estimate the model parameter Peclet number (Pe) values as a fitted parameter with the measured data, using the gold partition method for nonlinear programming strategy inequation restrict conditions. The ADM gave better fits to the experimental data at high axial locations and lower superficial gas velocity (UG) for an EL-ALR used with a large L/DR ratio. A synergistic effect of ULd, αGr, Pe, solids loading (SL), and sparger designs on the performance of an EL-ALR was observed in our experiments. The sparger designs were determined to have a noticeable effect on the αGr and Pe in the lower gas velocity and lower solid loading ranges (UG < 0.025 m/s and SL < 2%), but only a slight effect in the high gas velocity and high solid loading ranges (UG > 0.030 m/s and SL > 3%). However, the effect of sparger designs on the ULd is greater in the gas velocity from 0.025 m/s to 0.045 m/s. For the lower solids loading, the increase of orifice diameter leads to a decrease in αGr. This is in accordance with what was presented in the gas−liquid two-phase system. Moreover, the influence of orifice diameters of the spargers is negligible for solids loading of >3%. Although the Pe values decreased with the operating gas velocity, the gas velocity change from 0.03 m/s to 0.04 m/s yielded lower Pe values, as a result of the reduced bubble size. As the gas velocity further increased to 0.06 m/s, the αGr and the ULd values increased, while the Pe values negligibly increased. For a gas−liquid two-phase system, Pe decreases with the orifice diameter and, for 1% of solids, Pe is also lower for sparger P-2 (ϕ 0.6 mm) than for sparger P-1 (ϕ 0.3 mm). For higher amounts of solids (3%), Pe does not have a defined trend. In addition to the gas velocity and sparger design effects, the solids loading had the effect of decreasing the ULd values, while such effect became small and flattened at high solid loadings. The ULd values, especially with VO = 100%, are ~20% lower in three-phase flow than that in two-phase flow. In addition, the ULd profiles in three-phase flow are flatter than that in two-phase flow with VO = 50%−100%, actually showing a parabolic shape rather than the almost linear one encountered in two-phase flow. This is very important for design and optimum operation that are used to systemically investigate the synergistic effect of ULd, αGr, Pe, solid loading (SL), and sparger designs on hydrodynamic performance of an EL-ALR.