Hydrodynamic phonon drift and second sound in a (20,20) single-wall carbon nanotube

Abstract

Two hydrodynamic features of phonon transport, phonon drift and second sound, in a (20,20) single-wall carbon nanotube (SWCNT) are discussed using lattice dynamics calculations employing an optimized Tersoff potential for atomic interactions. We formally derive a formula for the contribution of drift motion of phonons to total heat flux at steady state. It is found that the drift motion of phonons carries more than $70%$ and $90%$ of heat at 300 and 100 K, respectively, indicating that phonon flow can be reasonably approximated as hydrodynamic if the SWCNT is long enough to avoid ballistic phonon transport. The dispersion relation of second sound is derived from the Peierls-Boltzmann transport equation with Callaway's scattering model and quantifies the speed of second sound and its relaxation. The speed of second sound is around 4000 m/s in a (20,20) SWCNT and the second sound can propagate more than 10 \textmu{}m in an isotopically pure (20,20) SWCNT for frequency around 1 GHz at 100 K.