Abstract

Carbon nanotube supported ruthenium catalysts, assembled at the water/oil interfaces, show excellent activity and selectivity for the hydrodeoxygenation of the bio-oil model compound of vanillin under mild conditions (1MPa, 150°C). Based on a direct fluorescence image, the Ru/CNT catalysts are mainly distributed on the surface of the emulsion droplets, forming a Pickering emulsion. Simultaneous reaction and separation of the products are achieved in the constructed emulsions, which have great potential in the simplifications of the isolation and purification stages for bio-oil refining.

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