Abstract
Treatment of (η5-X-substituted-cyclohexadienyl)tricarbonylmanganese complexes (X = alkoxy, halogeno, dimethylamino and thio) with hydrides and a proton source gave η5-cyclohexadienyl complexes resulting from a cleavage of the C−O, C−Cl, C−N and C−S bonds: The η3-substituted cyclohexenyl intermediates underwent elimination of an agostic hydrogen and the alkoxy, halogeno, amino, or thio group.
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