Hydroclimate reconstruction through MIS 3 in the Middle Paleolithic site of Crvena Stijena (Montenegro) based on hydrogen-isotopic composition of sedimentary n-alkanes

Abstract

This study presents a hydroclimatic reconstruction from Crvena Stijena (Montenegro, Balkan Peninsula), a rock shelter that has yielded evidence for Middle Paleolithic human occupation. The integration of lipid biomarkers, hydrogen (δD) isotopic compositions of n-alkanes, and organic elemental geochemistry in the 7-m deep vertical sedimentary sequence enables reconstruction of the main hydrological and environmental changes during the MIS 3 and their correlation with the presence at the site. We apply agglomerative hierarchical clustering and principal component analysis to the geochemical, molecular, and stable isotopic data to obtain a robust hydrological record. We find evidence of three aridity trends from the studied period, one of them correlated with the Heinrich Event 5, and humid and cold-temperate conditions in archaeology-rich layers. Our dataset also contributes to the knowledge of past hydrological variability in the Balkan Peninsula, a sensitive area to short-lived climatic shifts, and overall, in the Mediterranean region during the last glacial/interglacial cycle.