Hydrochemical Processes and Environmental Isotopic Study of Groundwater in Kuwait

Abstract

The present paper studies the hydrochemical processes and the isotopic characteristics of the main aquifers, the Kuwait Group and Dammam aquifers in the State of Kuwait. The water chemical types are dominantly NaCl and Na2SO4 in the Kuwait Group aquifer and Na2SO4, CaSO4, and NaCl in the Dammam Limestone aquifer. The groundwater of the Kuwait Group aquifer is supersaturated with respect to quartz and calcite, and near saturation with respect to aragonite, but under-saturated with respect to anhydrite, dolomite, gypsum, and halite. While the groundwater of the Dammam aquifer is strongly under-saturated with respect to anhydrite, halite, and gypsum and is supersaturated with respect to quartz, dolomite, aragonite, and calcite. The saturation indices of the calcite and dolomite are increased in the direction of flow from southwest toward north-northeast. Al-Rawdhatain and Umm Al-Aish groundwater samples lie near the meteoric water line. They represent the effect of recharge by rainfall during pluvial period. The brackish palaeo-groundwater of the Dammam aquifer has low values of δ18O (−4.5 per mil) and δD (−35 per mil), which reveal that these waters are related to the palaeo-water from the cool wet period in the eastern Arabia 11,000 to 60,000 years B.P. The investigated brackish groundwater samples showed that the deuterium excess values are much lower than that of the Mediterranean areas. This may suggest that the evaporation was a prevailing process before the infiltration to the aquifers.