Abstract

An additive‐free copper catalytic system was used to perform the addition of (hetero)aryl nucleophiles to N‐allenyl derivatives. This intermolecular C–C bond formation occurs with both complete regio‐ and stereoselectivity to afford the linear (E) allylic product with moderate to excellent yields. This atom economical method is the first example of hydroarylation of allenes catalyzed by copper.

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