Abstract

During recent decades, argillaceous sedimentary formations have been studied as potential host formations for the geological disposal of long-living and heat-emitting radioactive waste—Boom Clay in Belgium and Opalinus Clay and Brown Dogger in Switzerland. A significant issue in the long-term performance of these potential host rocks concerns the generation and transport of gases. The pressure resulting from the generation of gas in an almost impermeable geological medium in the near field of a repository will increase. Under high gas pressures, the mechanical and hydraulic properties of the host rock are expected to change significantly. Preferential gas pathways may develop which exploit material heterogeneity, anisotropy (bedding planes), rock discontinuities, or interfaces between the different components of the repository, and may eventually lead to the release of the produced gases. Gas flow through these clayey rocks is investigated on the basis of laboratory work. Priority has been given to studying the volume change response of these initially water-saturated materials through relatively fast and controlled volume-rate gas injections. The effect of the gas injection rate, the confining pressure and the bedding orientation on the gas transport properties have been studied with particular attention paid to the coupling with strain behaviour. The results have shown features common to the three formations concerning the gas transfer process through preferential pathways, despite their initially differential properties.

Highlights

  • Radioactive wastes conditioned for deep geological disposal in low-permeability formations will produce a significant amount of gas as a result of the anaerobic corrosion of metals, degradation of organic matter (whichClay-rich rocks have been identified as a class of candidate host rock formations in radioactive waste disposal,1 3 Vol.:(0123456789)L

  • It is essential to take into account that argillaceous rocks display a high initial suction level due to the significant stress relief upon sampling, despite being close to saturation

  • The confining pressure reached before the air injection was 15 Mercury Intrusion Porosimetry (MIP) (nm) air-entry value (AEV) (MPa), but in the case of Opalinus Clay formation (OPA) samples, another injection was performed at a higher confining pressure of 19 MPa to study its influence

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Summary

Introduction

Radioactive wastes conditioned for deep geological disposal in low-permeability formations will produce a significant amount of gas as a result of the anaerobic corrosion of metals (which produces ­H2), degradation of organic matter (whichClay-rich rocks have been identified as a class of candidate host rock formations in radioactive waste disposal,1 3 Vol.:(0123456789)L. Clay-rich rocks have been identified as a class of candidate host rock formations in radioactive waste disposal,. Clay-rich materials' excellent radionuclide retention behaviour entails low gas transport capacity. After repository closure, the accumulation of corrosion and degradation gases, added to the build-up of excessive gas pressures on the backfilled repository structures, could impair the performance of long-term safety functions for the EBS and host rock, respectively. The development of a mechanistic understanding of the release of gases from the backfilled structures through argillaceous host rock formations has been addressed in various national radioactive waste disposal programmes (e.g., Marschall et al 2005; ONDRAF/NIRAS 2011) and on international RD&D platforms for radioactive waste management organisations worldwide [e.g., EUP7-FORGE/(Shaw 2013)]. Laboratory data that might facilitate the development of conceptual models for predicting the long-term behaviour of the repositories are scarce

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