Hydration Characterization of Two Generations of MTA-Based Root Canal Sealers

Abstract

Since the setting characterization of a root canal sealer has an impact on its biological behavior of final obturation, this study evaluated the setting characterization of mineral trioxide aggregate MTA-Fillapex versus MTA-Bioseal compared with epoxy resin (Adseal) root canal sealers. Freshly mixed sealer was inserted into the mold (n = 10). The initial and final setting times were evaluated using a Vicat needle and were then statistically analyzed by one-way ANOVA at p < 0.05. The raw pastes and the stages of the setting reaction were analyzed using Fourier Transform Infrared (FTIR) Spectroscopy. The phase compositions were evaluated using X-ray diffraction (XRD). A significant and fast setting time was recorded by Adseal (4.7 ± 0.46 h) followed by MTA-Bioseal (11.4 ± 1.34 h) at p < 0.001. The MTA-Fillapex did not set completely in three months. The FTIR and XRD of both MTA-Bioseal and Adseal detected bands of the polymerized phases, while those of MTA-Fillapex detected partial polymerization with a low percentage of polymerized silica. MTA-Bioseal and Adseal met the ISO standards for setting times. However, MTA-Fillapex did not fulfill the ideal requirement for the sealer. Although the raw pastes of both MTA-sealers had nearly similar compositions, they behaved differently during the hydration reaction. MTA-Bioseal set completely, while MTA-Fillapex was not completely set.