Hydration behavior of spinel containing high alumina cement from high titania blast furnace slag

Abstract

Hydration behavior of the spinel containing high alumina cement prepared from high titania blast furnace slag via smelting reduction method is studied. Cooling condition has considerable effect on the phase compositions and hydration behavior of the prepared cements. Hydraulic CA, CA2, inert spinel and gehlenite are the main mineral phases of the naturally cooling cement. Glassy phase, CA and some spinel are the main phases of the splat cooling cement. Both of the prepared cements have controllable setting time, water requirements. Strength of splat cooling cement develops slowly than naturally cooling cement. The naturally cooling cement has satisfactory compressive strength, which is higher than splat cooling cement, but lower than commercial CA80 and Secar71. XRD and SEM observation confirms that CAH10 is the main hydrate of splat cooling cement. Metastable CAH10, C2AH8, are the main hydrates of naturally cooling cement, which will convert to stable C3AH6 with continuing hydration.