Hybridization of Mn/Ta bimetallic oxide and mesh-like porous bio-carbon for boosting copper reduction for D35/Y123-sensitized solar cells and hydrogen evolution

Abstract

Developing high-performance and low-cost catalysts for replacing Pt-based catalysts is a significant challenge for solar cells and water splitting applications. In this work, a bifunctional hybrid catalyst of MnTa 2 O 6 @MPC (MPC: mesh-like bio-based porous carbon) was synthesized, using a co-precipitation approach. Benefiting from the high specific surface area (332.743 m 2 g −1 ), integrating the merits of the electrical conductivity of MPC, the outstanding electrocatalytic ability of MnTa 2 O 6 , and the synergistic effect between MnTa 2 O 6 and MPC, the catalytic activity of MnTa 2 O 6 @MPC was significantly enhanced. To boost the photovoltaic performance of dye-sensitized solar cells, a novel Cu 2+ /Cu + redox mediator and dye (Y123, D35) were adopted for replacing the traditional I 3 - /I - redox mediator and N719 dye, respectively. The resulting advanced solar cell with the Cu 2+ /Cu + redox mediator based on the MnTa 2 O 6 @MPC counter electrode catalyst exhibited a photovoltage of ~0.88 V, and cell efficiencies of 3.41% and 1.92% for the D35 and Y123 dye systems, respectively, which are respectively 16% and 8% higher than that of Pt. MnTa 2 O 6 @MPC also exhibited significant catalytic ability for hydrogen production, yielding a small overpotential of 141.9 mV at a current density of 10 mA cm −2 and a small Tafel slope of 105.0 mV dec −1 in an alkaline medium. This work provides promising guidance for designing bifunctional hybrid electrocatalysts for high-performance new energy devices. ● MnTa 2 O 6 @mesh-like porous carbon is prepared by a co-precipitation method. ● MnTa 2 O 6 @MPC is served as a bifunctional catalyst in DSSC and HER systems. ● Advanced DSSC with novel D35/Y123 dye and copper redox couple is fabricated. ● PCE of DSSCs (D35 dye) with MnTa 2 O 6 @MPC is 16% high than that of DSSCs with Pt. ● MnTa 2 O 6 @MPC obtained a low overpotential of 141.9 mV in alkaline HER.