Abstract
Reactions between 1,2-bis(pyridinium)ethane bromide ((BPE)Br2) and [BiCl6]3−/[BiBr6]3− in HCl or HBr results in isostructural binuclear complexes (BPE)2[Bi2X10] (X=Cl (1) and Br (2)) which were characterized by X-ray diffractometry, IR and Raman spectroscopy. Both complexes manifest orange-red luminescence in solid state.
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