Hybrid salts of binuclear Bi(III) halide complexes with 1,2-bis(pyridinium)ethane cation: Synthesis, structure and luminescent behavior

Sergey A Adonin,Marianna I Rakhmanova,Denis G Samsonenko,Maxim N Sokolov,Vladimir P Fedin

doi:10.1016/j.ica.2016.06.010

Hybrid salts of binuclear Bi(III) halide complexes with 1,2-bis(pyridinium)ethane cation: Synthesis, structure and luminescent behavior

Sergey A Adonin, Marianna I Rakhmanova + Show 3 more

https://doi.org/10.1016/j.ica.2016.06.010

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Journal: Inorganic chemistry communications	Publication Date: Jun 6, 2016
Citations: 46

Affiliation: Novosibirsk State University, Siberian Branch of the Russian Academy of Sciences, Nikolaev Institute of Inorganic Chemistry

#Luminescence In Solid State #Ethane Bromide + Show 8 more

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Abstract

Reactions between 1,2-bis(pyridinium)ethane bromide ((BPE)Br2) and [BiCl6]3−/[BiBr6]3− in HCl or HBr results in isostructural binuclear complexes (BPE)2[Bi2X10] (X=Cl (1) and Br (2)) which were characterized by X-ray diffractometry, IR and Raman spectroscopy. Both complexes manifest orange-red luminescence in solid state.

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