Abstract
The development of hydrophobic composite coatings is of great interest for several applications in the aerospace industry. Functionalized microparticles can be obtained from waste fabrics and employed as fillers to prepare sustainable hydrophobic epoxy-based coatings. Following a waste-to-wealth approach, a novel hydrophobic epoxy-based composite including hemp microparticles (HMPs) functionalized with waterglass solution, 3-aminopropyl triethoxysilane, polypropylene-graft-maleic anhydride, and either hexadecyltrimethoxysilane or 1H,1H,2H,2H-perfluorooctyltriethoxysilane is presented. The resulting epoxy coatings based on hydrophobic HMPs were cast on aeronautical carbon fiber-reinforced panels to improve their anti-icing performance. Wettability and anti-icing behavior of the prepared composites were investigated at 25 °C and -30 °C (complete icing time), respectively. Samples cast with the composite coating can achieve up to 30 °C higher water contact angle and doubled icing time than aeronautical panels treated with unfilled epoxy resin. A low content (2 wt %) of tailored HMPs causes an increase of ∼26% in the glass transition temperature of the coatings compared to pristine resin, confirming the good interaction between the hemp filler and epoxy matrix at the interphase. Finally, atomic force microscopy reveals that the HMPs can induce the formation of a hierarchical structure on the surface of casted panels. This rough morphology, combined with the silane activity, allows the preparation of aeronautical substrates with enhanced hydrophobicity, anti-icing capability, and thermal stability.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.