Hybrid forward osmosis/membrane distillation integrated with anaerobic fluidized bed bioreactor for advanced wastewater treatment

Abstract

Forward osmosis (FO)-membrane distillation (MD) process was integrated with anaerobic fluidized bed bioreactor (AFBR) to advance wastewater treatment. Low removal efficiency of nutrients such as ammonia nitrogen was improved significantly by combining FO-MD process with AFBR. The MD membrane was applied to concentrate the draw solution (DS) which can be diluted by FO filtration. By using 1 M of NaCl as DS, about 80% of ammonia nitrogen was further removed by the FO membrane while the phosphorous was removed almost completely (99%). However, the accumulation of ammonia nitrogen in DS and the reverse salt flux through the FO membrane was unavoidable. Nevertheless, combining MD membrane produced excellent removal efficiency yielding only 4 and 5.6 mg/L of ammonia nitrogen and chemical oxygen demand (COD) in MD permeate, respectively at 15 ℃ of transmembrane temperature. Alternatively, there is the possibility that the FO-MD process can be superior to concentrate resources such as nitrogen and phosphorous present in AFBR. The reverse salt flux from DS into AFBR bulk suspension did not show adverse effects on the performances of bioreactor with respect to COD removal efficiency, conductivity and methane production during operational period. Deposit of the fouling layer on FO membrane was also observed, but the fouling on MD membrane was not severe probably because crystallization rate could be retarded by diluting the DS during FO filtration.