HRTEM and EELS characterization of atomic and electronic structures in Cu/α-Al 2O 3 interfaces

Abstract

Interfacial atomic structures of Cu/Al 2O 3(0 0 0 1) and Cu/Al 2O 3( 1 1 2 ¯ 0 ) prepared by the pulsed-laser deposition technique were characterized by high-resolution transmission electron microscopy (HRTEM). It was found that (1 1 1) and (0 0 1) planes of Cu were epitaxially oriented to Al 2O 3(0 0 0 1) and Al 2O 3( 1 1 2 ¯ 0 ) planes, respectively. Chemical bonding states at the interfaces were analysed by electron energy-loss spectroscopy (EELS). In oxygen–K edge energy-loss near-edge structure (O–K ELNES) of the Cu/Al 2O 3(0 0 0 1) and Cu/Al 2O 3( 1 1 2 ¯ 0 ) interfaces, a shoulder peak appeared at the lower energy side of the main peak. This indicates that Cu–O interactions were formed across these Cu/Al 2O 3 interfaces. In fact, the simulated HRTEM images based on the O-terminated interface models agreed well with the experimental ones. It can be concluded that the O-terminated interfaces were formed in the present Cu/Al 2O 3 interfaces.