Abstract
HRP-catalyzed polymerization of sugar-based phenols prepared by the reaction of sugar-lactones with tyramine was carried out in a buffer (pH 7)/organic solvent (1:1, v/v) mixture. When 1,4-dioxane, DMSO and alcohols such as methanol were used as organic solvents, the conversion rate was 10–20% and the molecular weight ( M n) of polyphenols was about 2500 in all solvents. The type of sugar moiety contained in phenol derivatives had little effect on the polymerization. The conversion rate and M n increased in the presence of a lipid such as AOT (dioctyl sulfosuccinate). Maltose-based polyphenol showed the strongest interaction with concanavalin A.
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