Abstract
Zinc-thiazole is a new fungicide that was independently developed in China and has a high efficiency and low toxicity. A modified derivatization method was established to measure zinc-thiazole in foods of plant origin. Zinc-thiazole decomposed into 2-amino-5-mercapto-1,3,4-thiadiazole (AMT) under alkaline conditions, and the AMT was extracted with acidic acetonitrile (pH = 3). The AMT was quantitated by HPLC–MS/MS, and then the amount of zinc-thiazole residue was calculated. Good linearity (R2 > 0.9997) was obtained in 0.001–1 mg/L. The limit of quantification of zinc-thiazole was 0.02 mg/kg in peaches, grapes, brown rice and soybeans. A qualified accuracy (recoveries of 75%–90%) and precision (RSD of 1%–5%) were obtained at three fortified levels. This method was applied to peach samples collected from farmland, and the zinc-thiazole residues complied with the residue limits. In the future, this method could be used to analyze residues and in the risk assessment of metal-thiazole fungicides.
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