Abstract

This research paper summarises the practical relevance of additive manufacturing with particular attention to the latest laser powder bed fusion (L-PBF) technology. L-PBF is a promising processing technique, integrating intelligent and advanced manufacturing systems for aerospace gas turbine components. Some of the added benefits of implementing such technologies compared to traditional processing methods include the freedom to customise high complexity components and rapid prototyping. Titanium aluminide (TiAl) alloys used in harsh environmental settings of turbomachinery, such as low-pressure turbine blades, have gained much interest. TiAl alloys are deemed by researchers as replacement candidates for the heavier Ni-based superalloys due to attractive properties like high strength, creep resistance, excellent resistance to corrosion and wear at elevated temperatures. Several conventional processing technologies such as ingot metallurgy, casting, and solid-state powder sintering can also be utilised to manufacture TiAl alloys employed in high-temperature applications. This chapter focuses on compositional variations, microstructure, and processing of TiAl alloys via L-PBF. Afterward, the hot corrosion aspects of TiAl alloys, including classification, characteristics, mechanisms and preventative measures, are discussed. Oxidation behaviour, kinetics and prevention control measures such as surface and alloy modifications of TiAl alloys at high temperature are assessed. Development trends for improving the hot corrosion and oxidation resistance of TiAl alloys possibly affecting future use of TiAl alloys are identified.

Highlights

  • Titanium aluminide (TiAl) is a member of group material referred to as intermetallics, consisting of various metals resulting in ordered crystallographic structures formed when the concentration of the alloy exceeds the solubility limit [1]

  • The four significant microstructures which may result in a Ti-Al system are namely, duplex (DP), near-gamma (NG), nearly lamellar (NL) and fully lamellar (FL)

  • Hot corrosion exists as Type I or Type II (Low-Temperature Hot Corrosion), with the former occurring above 800–950°C and the latter at 600–750°C [88, 89]

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Summary

Introduction

Titanium aluminide (TiAl) is a member of group material referred to as intermetallics, consisting of various metals resulting in ordered crystallographic structures formed when the concentration of the alloy exceeds the solubility limit [1]. Corrosion make TiAl replacement candidates for nickel-based superalloys used in the aerospace and automotive industries [2–4] One such alloy tried and tested by General Electric [5] for commercial turbofan engines is Ti-48Al-2Cr-2Nb. Despite the attractive high-temperature properties attained in research to date, the inherent poor ductility of TiAl at ambient temperatures remains a concern [6]. To overcome problems associated with conventional processing, such as microstructural inconsistencies inherited from solidification and phase evolutions resulting in the scattering of mechanical properties, heat treatment cycles are often designed [18–21].

Phase evolutions
Microstructure-mechanical property relations
Process overview
Research milestones
Definition
Characteristics
High-temperature hot corrosion (HTHC)-type I
Stage II
Stage IV
Low-temperature hot corrosion (LTHC)-type II
Mechanisms
Laboratory testing techniques
Proper alloy selection
Protective coatings
Cleaning hot parts and air filtering
Hot corrosion studies for TiAl alloys
Oxidation behaviour in TiAl alloys
Oxidation kinetics of TiAl alloys
Effect of alloy modifications on the oxidation resistance of TiAl
Conclusions
Full Text
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