Abstract

Mn4+ doped and Pr3+,4+, Nd3+ co-doped MgAl2Si2O8-based phosphors were first of all synthesized about 1300°C. They were characterized by thermogravimetry (TG), differential thermal analysis (DTA), X-ray powder diffraction (XRD), photoluminescence (PL) and scanning electron microscopy (SEM). The luminescence mechanism of the phosphors, which showed broad red emission bands in the range of 610–715nm and had a different maximum intensity when activated by UV illumination, was discussed. Such a red emission can be attributed to the intrinsic d–d transitions of Mn4+.

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