Host-guest doped room/high-temperature phosphorescence of diarylfuro[3,2-b]pyridine derivatives

Abstract

Due to the high temperature that can easily lead to non-radiative transitions of triplet excitons, obtaining high-temperature phosphorescence (HTP) materials is challenging. Herein, using diarylfuro[3,2-b]pyridines as the guest molecules and polyacrylic acid (PAA) as the host molecule, the two-component doped materials exhibit green room-temperature phosphorescence (RTP) with afterglow times of 2–8 s, delayed lifetimes of 256–939 ms, and phosphorescence quantum efficiencies of 140.3–21.2 %, and green HTP emissions with 2 s afterglow and 208 ms delayed lifetime at 373 K. The HTP activity of the doped system originates from the rigid environment provided by PAA, planar and rigid molecular structures of diarylfuro[3,2-b]pyridines, and strong interactions between PAA and diarylfuro[3,2-b]pyridines. Furthermore, using organic small molecules as the reference host molecules, compared to benzophenone, 5-methylphthalic anhydride, and butane-1,2,3,4-tetracarboxylic acid with chemical structures similar to PAA result in better RTP/HTP properties, revealing that strong interactions between host and guest molecules play a very important role in ultralong phosphorescence emissions of these host–guest doped materials. Moreover, these doped materials based on diarylfuro[3,2-b]pyridines can be developed as advanced anti-counterfeiting and encryption materials. This result provides valuable reference for developing excellent RTP/HTP materials based on N,O-containing fused-ring compounds.