Host-Guest Chemistry in Binary and Ternary Complexes Utilizing π-Conjugated Carbon Nanorings.

Abstract

The carbon nanorings, possessing a radial π system, have garnered significant attention primarily due to their size-dependent photophysical properties and the presence of a unique curved π-conjugated cavity. This is evidenced by the rapid proliferation of publications. Furthermore, the integration of building blocks into CPP skeletons can confer [n]CPPs with novel and exceptional photophysical and electronic characteristics, as well as chiral properties and host-guest interactions, thereby augmenting the diversity of [n]CPPs. Notably, the curved π surface structures and concave cavity of carbon nanorings enable them to host aromatic or non-aromatic guests with a complementarily curved surface, resulting in interesting binary or ternary complexes. This review provides a comprehensive treatment of literature reports on binary and ternary complexes, focusing on both their host-guest interactions and properties. It is important to note that the scope of this review is limited to host-guest chemistry in binary and ternary complexes based on π-conjugated carbon nanorings.