Abstract
The literature data on the liquid-phase homolytic isomerization, addition, substitution, and oxidation reactions of 1,3-dioxacyclanes are examined. The problems involved in the formation, stabilities, kinetics, and mechanisms of the transformations of free radicals in a series of cyclic acetals are discussed. Possibilities for the application of the homolytic transformations of 1,3-dioxacyclanes in organic synthesis are demonstrated.
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