Abstract
Fragmentation of the (R)-(+)-1-phenyl-1-propanol radical cation ([(BZC2H5)R]+) is markedly affected by asymmetric microsolvation (see picture). The CαCβ bond cleavage in the heterochiral [(BZC2H5)R.BDSS]+ cluster is more efficient than in the homochiral [(BZC2H5)R.BDRR]+. The difference is ascribed to structural factors that make BDSS a better H-bond acceptor than BDRR in their adducts with [(BZC2H5)R]+. BZ=PhCHOH, BD=2,3-butanediol.
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