Abstract

The catalytic activity of the Rh 2Cl 2(C 8H 14) 4 + ▪ and RhCl 2(C 4H 7) + ▪ systems (R = n-propyl, n-butyl, n-amyl, cyclohexyl; C 8H 14 = cyclooctene; C 4H 7 = 2-methylallyl) in the homogeneous hydrogenation of olefins was examined. The influence of the R substituents and of the Rh:ligand ratio on the hydrogenation rate of various olefins was defined.

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