Abstract
Pyridine bases picolinic acid, 2,2′-bipyridyl, 1,10-phenanthrolinc, imidazole and N-methylimidazole efficiently catalyse the carboxylato bound chromium (V) oxidation aryl methyl sulfides. The catalysis is explained in terms of intermeidate Cr(V)-catalyst and Cr(V)-catalyst-substrate complexes. The products, sulfoxide and Cr(III), are formed due to ligand coupling of O and sulfur center of sulfide. The catalysed Cr(V) oxidation of organic sulfides in accordance with the reactivity - selectivity principle.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
