Abstract
The laser light scattering intensity fluctuations of supercooled liquid o-terphenyl at temperatures between 12 and −15 °C have been studied using the photon-correlation technique. The time correlation functions obtained using the VV and VH scattering configurations at 90° scattering angle show a wide distribution of relaxation times. Angular-dependent measurements at 45°, 90° and 135° scattering angles show that the time correlation functions for VH and for VV are independent of scattering angles. The VV and VH correlation functions cannot be fit to a bimodal distribution function; neither can they be fit to a cumulant expansion expression with less than four cumulants, but they can be satisfactorily fit to the William–Watts distribution function. The mean relaxation times derived for both isotropic and anisotropic scattering processes from the VV and VH correlation functions are nearly equal. The temperature dependence of the relaxation times cannot be described by an Arrhenius equation with a constant activation energy. The average orientational relaxation times change by more than ten orders of magnitude in the temperature range between 147 and −16 °C but the temperature dependence of the orientational relaxation times over this wide dynamic range can be excellently correlated with the modified Debye–Stokes–Einstein equation. The closeness of the mean orientational relaxation time to the mean structural relaxation time is interpreted as due to strong rotation–translation coupling in the viscoelastic state. It is found that within the dynamic range of the autocorrelator, the collective shear wave plays no role in the time dependence of the VV and VH correlation functions. Quentrec’s theory of viscoelasticity based on the coupling of the shear wave to local translational order and orientational order is found to disagree with the experimental result. Comparison with the dielectric relation time data shows that in o-terphenyl the dielectric relaxation and the present light beating techniques probe different types of motions.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
