Abstract
A pair of enantiopure chiral porous coordination polymers (PCPs) with a rare utk topology were prepared using derivatives of L-/D-alanine and Zn(CH3COO)2·2H2O. The framework integrated two types of parallel and uniform 1D channels that were constructed by self-stranding of three equal helical chains and a single helical chain. Among them, the right-handed PCP D-NTU-18 showed enhanced enantioseparation towards racemic 1-phenyl-1-propanol.
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