Abstract
Reactions of achiral ligand N2,N6-bis((pyridin-2-yl)methyl)pyridine-2,6-dicarboxamide (L) with AgAsF6 and AgSbF6, respectively, produced [AgL] n · nAsF6 (1) and [AgL] n · nSbF6 (2), where helically chiral 1-D coordination polymers conglomerate through complicated supramolecular interactions to form two 3-D enantiomerically chiral architectures with unusual (10,3) nets, showing spontaneous chiral resolution. Compounds 1 and 2 emit ligand-centered violet-fluorescence with strong intensities and double peaks centered at 329 and 344 nm.
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