Abstract

Homo- and copolymerization of ethylene and propylene was carried out using a heterogeneous Cr(Ch 3 COO) 3 AlEt 2Cl catalytic system in toluene at 40°C. Homopolymerization was studied at atmospheric pressure and followed by measuring the volume of monomer consumed. Copolymerization was carried out at low pressure in a closed system and the progress of the reaction was studied by monitoring the change in monomer pressure. Random copolymers were obtained despite the catalytic system being heterogeneous.

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