Abstract
New modifications of KInS2 and RbInS2 were found after high pressure treatment and quenching to ambient conditions. The tetragonal modifications KInS2-II and RbInS2-II are isotypic with TISe. KInS2-II is metastable at all p,T-conditions investigated. The stable high pressure modification KInS2-III has a-NaFeO2-structure. Pressure treatment of CsInS2 yielded an unknown phase with a diffuse X-ray pattern.
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