Abstract
The photodecomposition of diluted aqueous solutions of acridine and aminacrine in the presence of hydrogen peroxide was studied. Irradiation was carried out with a low pressure mercury vapour lamp. The kinetic model describes the photodegradation rate of the organic compound with respect to the technological parameters of the reactor and provides the reaction rate constants of hydroxyl radicals towards these two molecules. This model was extented to high hydrogen peroxide concentrations ([H2O2] > 200 μmol/l) by considering the reactivity of hydroxyl radicals towards hydrogen peroxide. This assumption allows us to define an optimal hydrogen peroxide concentration.
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