HKUST-1 in-situ loaded ultrastable covalently crosslinked agarose aerogel with solvothermal for highly efficient removal of methylene blue.

Abstract

A new HKUST-1@covalently crosslinked agarose aerogel (HKUST-1@CCAGA) was synthesized for the highly effective elimination of Methylene Blue (MB). Firstly, the covalently crosslinked agarose aerogel (CCAGA) was obtained by hydrothermal crosslinking reaction with epichlorohydrin (ECH) as crosslinker, which remained stabilized under hydrothermal and solvothermal conditions. Then, HKUST-1 was made to bind to CCAGA by in situ solvothermal assays, and the HKUST-1 loading rate reached 47.4 % based on thermogravimetric data and calculated using the cross over method. Meanwhile, the SEM exhibited the complete 3D honeycomb structure of CCAGA, and HKUST-1 particles uniformly distributed on its layers. Additionally, the specific surface area of HKUST-1@CCAGA can reached 648.59 m2·g-1. The HKUST-1@CCAGA composite was utilized for MB removal, achieving a high adsorption capacity of 424.30 mg·g-1 at pH 8. The adsorption of MB was also maintained at 80 % after 5 cycles of the experiment. The composite aerogel exhibits good recyclability and has excellent adsorption capacity.