Abstract

ABSTRACTThe oxygen partial pressure - temperature phase diagram of YBCO type superconductors reported before by us showed that the YBa2Cu4Ox phase formation from Y2Ba4Cu7Oz with CuO, as well as from YBa2Cu3Oy, with CuO are oxidation reactions. The total gas pressure - temperature phase diagram shows that the YBa2Cu4Ox, phase formation temperature from Y2Ba4Cu7Oz with CuO increases with increasing the total gas pressure. On this phase boundary line, the fugacity of oxygen increases with increasing the total gas pressure even at constant oxygen partial pressure.

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